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81.
Cover Picture: Ultrathin Coating of Confined Pt Nanocatalysts by Atomic Layer Deposition for Enhanced Catalytic Performance in Hydrogenation Reactions (Chem. Eur. J. 25/2016) 下载免费PDF全文
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The paper summarizes and discusses the recent advances of proteins as functional interlayers in organic field-effect transistors (OFETs). Specific focus is given on the proteins integrated into the device structure, either to act as dielectric materials or to perform as the functional interlayer between the dielectric and the organic semiconductor (OSC). The main emphasis is give to the location and the specific effect of protein layers in the structure of OFETs. Besides, the possibility of amyloid serving as useful building blocks for OFET is discussed. 相似文献
83.
Facile synthesis of thermosensitive functional polyaspartamide derivatives by click chemistry 下载免费PDF全文
Guangyan Zhang Yunti Zhang Yanfeng Chu Yingying Ma Renxi Zhuo Xulin Jiang 《Journal of polymer science. Part A, Polymer chemistry》2015,53(10):1296-1303
Biodegradable and thermosensitive polyaspartamide derivatives containing pendant azide groups P(Asp‐Az)X‐HPAs were synthesized from poly(l ‐succinimide) via the ring‐opening reaction with 2‐azidoethylamine (Az) and 5‐hydroxypentylamine (HPA). Then hydrophobic phenethyl (PEA) and imidazole (IMZ) moieties were introduced successfully with very high reaction efficiency above 90% to the side chains of P(Asp‐Az)X‐HPA by click reaction to obtain thermoresponsive polyaspartamide derivatives containing pendant aromatic rings P(Asp‐Az)X‐HPA‐PEAs and the thermo/pH‐responsive polyaspartamide derivatives containing pendant imidazole rings P(Asp‐Az)X‐HPA‐IMZs, respectively. The thermoresponsive behaviors of P(Asp‐Az)X‐HPA‐PEAs and P(Asp‐Az)X‐HPA‐IMZs were confirmed by dynamic light scattering (DLS) and transmittance measurements, and the cloud point can be tuned by designed amounts of azide groups and can be further adjusted by the grafting molar percentage of hydrophobic phenethyl or imidazole moieties to the side chains of P(Asp‐Az)X‐HPA via click chemistry. The pH‐responsive behavior of P(Asp‐Az)X‐HPA‐IMZs can also be tuned. These results indicate that the obtained polyaspartamide‐based functional polymers can be further functionalized with hydrophilic long PEG chain and/or targeted moieties via click chemistry for drug delivery. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 1296–1303 相似文献
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Highly fluorescent polycaprolactones decorated with di(thiophene‐2‐yl)‐diketopyrrolopyrrole: A covalent strategy of tuning fluorescence properties in solid states 下载免费PDF全文
Kai Wang Yimin Luo Shuo Huang Hongbin Yang Bin Liu Mingfeng Wang 《Journal of polymer science. Part A, Polymer chemistry》2015,53(8):1032-1042
Well‐defined 1,4‐diketo‐3,6‐di(thiophen‐2‐yl)pyrrolo[3,4‐c]pyrrole (DTDPP) labeled polycaprolactones (PCL) with different chain lengths were synthesized and characterized. The effect of polymer chain lengths on the optical properties of DTDPP in solid states was studied by UV‐Vis absorption spectroscopy as well as steady‐state and dynamic fluorescence spectroscopies. Our results indicate that when the PCL side chain is extended to a certain length, the intermolecular aggregation of DTDPP units can be reduced significantly due to segregation effect of PCL. This approach offers a new facile strategy to address the common problem of aggregation‐caused quenching existing in organic fluorophores. These highly fluorescent biodegradable PCL polymers may find broad biomedical applications such as fluorescence‐based bioimaging and tissue engineering. © 2015 Wiley Periodicals, Inc. J. Polym. Sci. Part A: Polym. Chem. 2015 , 53, 1032–1042 相似文献
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Asymmetric Michael Addition of Aldimino Esters with Chalcones Catalyzed by Silver/Xing‐Phos: Mechanism‐Oriented Divergent Synthesis of Chiral Pyrrolines 下载免费PDF全文
Xing‐Feng Bai Dr. Li Li Dr. Zheng Xu Dr. Zhan‐Jiang Zheng Prof. Dr. Chun‐Gu Xia Dr. Yu‐Ming Cui Prof. Dr. Li‐Wen Xu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(30):10399-10404
The mechanism‐oriented reaction design for the divergent synthesis of chiral molecules from simple starting materials is highly desirable. In this work, aromatic amide‐derived nonbiarylatropisomer/silver (silver/Xing‐Phos) complex was used to catalyze the Michael addition of glycine aldimino esters to chalcones and successfully applied to the subsequent cyclocondensation to afford substituted cis‐Δ(1)‐pyrroline derivatives with up to 98 % ee. Besides the inherent performance of the chiral Ag/Xing‐Phos catalyst system, it was found that the workup of such reactions played an important role for the stereoselective construction of stereodivergent Δ(1)‐pyrrolines, in which an epimerization of the cis‐Δ(1)‐pyrrolines to the trans‐isomers during was revealed. 相似文献
90.
Quantitative analysis of polyhexamethylene guanidine (PHMG) oligomers via matrix‐assisted laser desorption/ionization time‐of‐flight mass spectrometry with an ionic‐liquid matrix 下载免费PDF全文